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TheScientificWorldJOURNAL (ISSN 1537-744X)

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  Title: Smog Nitrogen and the Rapid Acidification of Forest Soil, San Bernardino Mountains, Southern California
  Authors:   Wood, Yvonne A.; Fenn, Mark ; Meixner, Thomas ; Shouse, Peter J.; Breiner, Joan ; Allen, Edith ; Wu, Laosheng  
  Journal:   TheScientificWorldJOURNAL  
  Year:   2007  
  Volume:   7  
  Supplement no.:   S1  
  Page Range:   175-180  
  Article Type:   Short Communication  
  Handling Editor:   Andrzej Bytnerowicz  
  Domains:    Atmospheric Systems ,  Soil Systems ,  Water Science & Technology ,  Environmental Systems & Tracers  
  DOI:   10.1100/tsw.2007.74  
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  Keywords:   Soil pH, nitrogen, soil hydrology, air pollution, forest soils, stone lines, geochemistry, landscape-atmosphere interactions  
     
 
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      Abstract  
      We report the rapid acidification of forest soils in the San Bernardino Mountains of southern California. After 30 years, soil to a depth of 25 cm has decreased from a pH (measured in 0.01 M CaCl2) of 4.8 to 3.1. At the 50-cm depth, it has changed from a pH of 4.8 to 4.2. We attribute this rapid change in soil reactivity to very high rates of anthropogenic atmospheric nitrogen (N) added to the soil surface (72 kg ha–1 year–1) from wet, dry, and fog deposition under a Mediterranean climate. Our research suggests that a soil textural discontinuity, related to a buried ancient landsurface, contributes to this rapid acidification by controlling the spatial and temporal movement of precipitation into the landsurface. As a result, the depth to which dissolved anthropogenic N as nitrate (NO3) is leached early in the winter wet season is limited to within the top ~130 cm of soil where it accumulates and increases soil acidity.  
     
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